Chem 131 Experiment : Soap Making (sopanification)

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چکیده

In this experiment we prepare soap from animal fat (lard) or vegetable oil. Animal fats and vegetable oils are esters of carboxylic acids; they have a high molecular weight and contain the alcohol, glycerol. Chemically, these fats and oils are called triglycerides (See chapter 18 of your text). The principal acids in animal fats and vegetable oils can be prepared from the natural triglycerides by alkaline hydrolysis (saponification). You may also choose to add a scent to your soap by adding an essential oil. You can purchase the scent you want to add or isolate it from the natural source using a process of steam distillation (see ‘Natural Product Isolation’ procedure at the end of this lab) % ChemDraw Laser Prep opyRight 1986, 1987, Cambridge Scientif ic Computing, Inc. userdict/chemdict 145 dict put chemdict b g n/version 24 def/b{bind def}bind def/L{load def}b/d/def L/a/add L/al/aload L/at/atan L/cp/closepath L/cv/curveto L/cw/currentlinewidth L/cpt/currentpoint L/dv/div L/dp/dup L/e/exch L/g/get L/gi/getinterval L/gr/grestore L/g /gsave L/ie/ifelse L/ix/index L/l/lineto L/mt/matrix L/mv/moveto L/m/mul L/n/neg L/np/newpath L/pp/pop L/r/roll /ro rotate L/sc/s ale L/sg/setgray L/sl/setlinewidth L/sm/setmatr x L/st/stroke L/sp/strokepat s/sub tr/tran f /xl/translate L/S{sf }b/dA{[3 S]}b/dL{dA dp 0 3 lW m put 0 setdash}d/cR 12 d/wF 1.5 d/aF 10 d/aR 0.25 d/aA 45 d nH 6 d/o{1 ix}b/rot{3 -1 r}b/x{e d}b/cm mt currentma rix d/p{tr round e round e itransform}b/Ha{ np 3 1 r xl dp s -.6 1.2 p mv 0.6 1.2 p l -.6 2.2 p mv 0.6 2.2 p l cm s s gr}b/OB{/bS x 3 ix 3 ix xl 3 -1 r s 3 1 r e s o o at ro d m e dp m a sqrt dp bS dv dp lW 2 m lt{pp lW 2 }if/bd x}b/DA{np 0 0 mv aL 0 aR aL m 180 A s 180 aA arc c fill}b/OA{np 0 cw -2 dv mv aL 0 R aL m 180 aA s 180 arc 0 cw -2 dv rlineto cp fill}b SA{aF m lW /a x aL 1 aR s m n 0 p mv rad 0 p l gs cm sm gr}b/CA{aF lW m/aL x aL 1 aR s m 2 v rad dp m o dp m s p 0 le{pp pp p}{sqrt at 2 m np rad 0 rad 180 6 r s 18 6 -1 r s arc gs cm sm st gr cp e at ro}ie}b/AA{np rad 0 rad 180 180 6 -1 r arc g cm sm st gr} /RA{l m/w x np rad w p v w w p l ad w mv w w n p l w 2 m dp p mv 0 0 p l w 2 m p n p l s }b/HA{lW m/w x np 0 0 p mv w 2 dp p w 2 w l rad w p l ra w n p l w 2 m w n p l w 2 m d n p l cp st}b/A 1{g 5 1 r 3 ix 3 ix x 3 -1 r s 3 1 e s o o at ro dp m e p sqrt rad x[{2.25 SA DA}{1.5 SA DA}{1 SA DA}{cw 5 m 3.375 SA DA}{cw 5 m sl 2.25 SA DA}{cw 5 m sl 1.5 SA DA}{270 CA DA}{180 CA DA}{120 CA DA}{90 CA DA}{3 RA} 3 HA} -1 270 CA DA}{1 -1 sc 180 CA DA}{1 -1 sc 120 CA DA}{1 -1 sc 9 CA DA}{6 R }{6 HA}{dL .25 SA DA}{dL 1.5 SA DA}{dL 1 SA DA}{2.25 SA OA {1.5 OA}{1 S O -1 c 2 25 SA OA}{1 -1 sc 1.5 S OA}{1 -1 c 1 SA O }{270 CA OA}{180 CA OA}{120 CA OA}{90 CA OA}{1 -1 sc 70 C OA}{1 -1 sc 180 CA OA}{ -1 sc 120 CA O }{ -1 sc 9 CA O }{1 -1 270 AA 1 -1 sc 180 AA {1 -1 sc 120 AA}{1 -1 sc 9 AA}]e g exe gr b/a {arcto 4{pp}rep at}b A 32 d/rO{4 lW m}b c{0 0 px dp py d m a sqrt 0 360 arc cm m gs s fill gr st}b/O A{ y px t ro x py dp m a sqrt dp r v{neg} f sc}b/Ov{Or 1 0.4 sc 0 0 1 0 360 arc m sm gs sg fill gr st}b/As {OrA 1 27 dv p s }b LB{9 -6 v 21 0 7 -8 27 0 cv 27 8 21 10 9 6 cv -3 2 -3 2 9 -6 cv cp}b/DLB{ v -4.8 4.8 l 8 8 -9.6 12 -9.6 16 8 c -9.6 2 . -8 24.6 -4 8 25 8 cv -1 6 27 1.6 27 4.8 25.8 v 8 24.6 9.6 2 .6 9.6 16.8 cv 9.6 2 8 8 4.8 4.8 v cp}b/ZLB{LB} dp 39 lt{Ar1 gs 5 1 r o o xl 3 -1 r e s 3 1 r s e o 0 lt o 0 lt ne/rev x d 0 lt{1 -1 sc neg}if/py x d 0 lt -1 1 n g} px x p[{ y 16 div dup 2 S lt{pp S}if/lp x p 0 p mv 0 p l 0 py p l lp py p l px lp s 0 p mv px 0 p l p y px lp s py p l sm s }{py 16 div u 2 S lt{ p 2 S}if/lp x lp p mv 0 0 py lp ac py 2 dv lp neg o lp a 0 py 2 dv 0 y lp ac py p py l a px lp s 0 p mv px 0 x py lp ac py 2 dv x l a o lp c x y 2 dv px py lp ac px y l s py lp ac m m t {py dp v y 8 A s 18 A arc st n px y s py 2 dv y A dp n g ar n st}{0 v py p px py px 0 p l s t}{px W 2 v lW -2 dv O dp rli eto x W dv rO a y lW 2 dv a a p l O W -2 dv a py lW 2 dv a rO p l lW -2 d py lW 2 dv a p l y l x py p px 0 p l cp fill 0 p 0 py p l px y p l x p l cp c m st}{0 rO mv 0 py px py r ac px y px 0 rO ac x 0 0 0 O c 0 0 py rO ac c s }{rO y p mv rO xl 0 py px py r ac p x 0 O ac px 0 0 0 rO ac rO n g d xl x py 0 rO ac c fill 0 rO p mv 0 py px y rO ac x py x 0 rO a px 0 0 0 rO 0 0 y rO a p st}{1.0 Ac}{0.5 Ac}{1 0 Ov}{ .5 Ov { sc LB 1 sg fill gr cm sm st}{A c LB s .5 g fill gr s s }{A LB gs .5 sg fi l gr gs cm sm st gr n -1 c LB 1 sg fi l g c sm st}{ B gs 0.5 sg fill r g c s st gr np -0.4 -0.4 sc LB gs sg fill gr cm m st}{As LB g 1 sg fill gr g cm sm s gr n .4 -0. sc LB g .5 sg fill g cm s st}{A c LB -1 -1 sc DLB gs 1 sg f ll g g cm m st gr n 90 o DLB sc LB 0. g fi l g m st}{ c g -1 c ZLB g fill gr cm sm st gr gs 0.3 1 0 2 0 360 a c gs 0.5 fill r cm t ZLB gs 1 g fill sm }{A g -1 -1 sc ZLB g 0.5 g fill gr c s st r g 0.3 s 0 12 3 r 1 sg f ll gr cm m st g ZLB gs .5 sg fill g cm sm t}{0 p v x y p l cm m t}{gs W 0 ne{b }{5 m ie 0 0 p mv px py l cm s t gr}{gs d 0 0 p m x py p l st r}{OrA 1 16 dv dp sc 1 0 1 0 ac 8 8 -1 ac ac 16 0 16 1 a cm s st}]e 39 g exec gr}ie}b/Cr{0 36 n r st b/DS{np l t}b/DD{ s L DS gr}b/ B{gs OB bW 0 ne{bW}{2 bd }ie sl np 0 mv 0 l st gr} /ap{e 3 ix e 2 x a}b/PT{8 OB 1 s b 0 0 p 3 1 3 1 r e s e p m 1 l 0 p v 1 0 p p l e n n 0 0 p ap mv a l p pp}b/DT{ s n PT m sm s g }b/Bd{[{pp}{[{DS g 2 OB n bW 0 ne bW 2 d /b x}if dp nH dv d -1 r o dv s{d bd bd n l}for t r g 1 B s np bW 0 ne{bW 2 dv/bd x}if 1 nH {nH v dp bd m wF o p mv n l}for c m s gr}{ DB}{gs 2 OB np l 2 dv o o n p v p l bW 0 ne{bW 2 d }{ i wF m o o l n gr}{ }{gs 2 OB/bL x bW ne{bW 2 /bd x}if n 0 p m bL bd 4 m v round 2 o o t{ }if pp cvi/nSq x b nSq 2 m dv d c nSq{. 35 .667 .8 5 .667 1 0 rcurveto .135 -.667 .86 -.6 7 1 rcu ve o}r e t c st r}]o g e 2 4 gi al p 5 -1 exe }{ l p 8 ix 1 q D } DS}i 5 -1 r 2 eq{DB}{DS}ie }{2 4 gi al p DT ]o 0 g exec}b/ S p mv cw W cW sl s cB 2 OB 0 0 v 0 p l cm sm cw 0 ne bW}{bd 2 m}ie cW 2 m a l s sl}b/CW{ 2 OB 1 c W lW 2 dv a n l bW ne{bW 2 dv bd}ie wF m W o n l e l c m m b C {n [{[ }{CS}{cB}{ W}{p }{cB CW p }{ B ]o 1 g 1 e 2 4 gi 5 1 r ex c}{a pp v CS p 4 g PT cw cW 2 m sl p s }]o s g ex c clip Ct{ s rot g bs ro g o CB 1 et ray l p ath ill 0 s tg y Bd gr}b/ D 8 di t /WI{ x dx ne{wy y wx dx s v x wy 1 wx 1 if lx ex {ly e s lx ex s d / 2 y lx /b2 w dx ne b2 b1 s 1 m2 dv}{wx}ie m b2 a}{ x d m b } W{gs w be in bs e g 4 gi l o o 4 r 3 -1 r s/wx x wy x bs e 2 4 gi l 4 r -1 /l x s/l x b 2 dv wF m o x at t ro tr/dy x/dx x ly lx t m ro tr n/ey n ex x np wx wy v WI p l n e x ey n ey dx n x dy n/ y lx ly WI cp fil end gr b In{ dx e{ y x s dv/ 1 x py 1 x m s/b x}if l 0 ne{ly lx dv 2 x ly ey 2 x x s s/ 2 x x { 2 b 1 dv}{ x ie BW{wD b i bs w s g/ wb 4 / X w 5 g/cY bb 4 cX eq b g cY q an { b 2 b 3 g bb 4 b g}i Y / y x X s/lx /w wb 2 X /wy wb 3 g Y s d 0 W 2 v ly x at mt ro tr/ey x/ex x bW wF m wy w ro tr/dy x/ x lW dv w x t ro tr wy a/ y wx a/px s X cY l p y p In l x l ey p l ex /ex x y n/ey dx n/dx dy y x wx 2 m wy 2 m py / y x l e ly e s l In p x py l c fi gr }b/D {bs{ p y e[]ty q 0 2 q{g 1 1 eq{dL}if 6 4 g l p S gr}{ g 3 eq 2 4 i l DT}{p }ie}ie {p }ie forall I{ ountto ark 1 g { rot{r}f r} }ie}b/DSt{o iX d iY x o/ X dp cY x v counttom rk e g 2 4 i al p o cX ne o Y ne r 4 r 4 1 r}if pp p / X x dp o iX eq o iY e a d {p l}i } e at p t} /SP{g / f W / W x ount 9 ge 7 ix 19 83746 eq and 7 r pp 6 2 o o xl 7 -1 r s e -1 r e 5 r dv e 5 r dv e neg e n e l {xl f 1 S d c current t i lW 4. et iterlimit np e 372 211 63 53 20 295 9 20 chemdict begin SP 516

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تاریخ انتشار 2010